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Phase-Transfer Catalysis : Fundamentals, Applications, and Industrial Perspectives - M. Halper
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M. Halper:

Phase-Transfer Catalysis : Fundamentals, Applications, and Industrial Perspectives - gebunden oder broschiert

1994, ISBN: 0412040719

[EAN: 9780412040719], Neubuch, [PU: Springer Netherlands], CHEMIE / LEBENSMITTELCHEMIE; POLYMERE - POLYMERISATION; ARBEITSSTOFF; MATERIAL; WERKSTOFF; ISOMER; OXIDATION; POLYMER; DISTRIBUT… Mehr…

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C.M. Starks, M. Halper:

Phase-Transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives (Hardback) - gebunden oder broschiert

1994, ISBN: 0412040719

[EAN: 9780412040719], Neubuch, [PU: Chapman and Hall, United Kingdom], Language: English. Brand new Book. Since 1971 when useful working concepts for the technique of phase-transfer catal… Mehr…

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C.M. Starks, M. Halper:
Phase-Transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives (Hardback) - gebunden oder broschiert

1994

ISBN: 0412040719

[EAN: 9780412040719], Neubuch, [PU: Chapman and Hall, United Kingdom], Language: English. Brand new Book. Since 1971 when useful working concepts for the technique of phase-transfer catal… Mehr…

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Halper, M., Starks, C.M.:
Phase-Transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives - gebunden oder broschiert

1994, ISBN: 9780412040719

Hardcover, Ex library copy with usual stamps/stickers Very Good: a copy that has been read, but is in excellent condition. Pages are intact and not marred by notes or highlighting. The sp… Mehr…

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Phase-transfer Catalysis by C.m. Starks Hardcover | Indigo Chapters
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Phase-transfer Catalysis by C.m. Starks Hardcover | Indigo Chapters - neues Buch

ISBN: 9780412040719

Fundamentals, Applications, And Industrial Perspectives | Phase-transfer Catalysis by C. m. Starks Hardcover | Indigo Chapters Books > Science & Nature > Science > Chemistry P10117, C.m.… Mehr…

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Phase-transfer Catalysis by C.m. Starks Hardcover | Indigo Chapters
Autor:
Titel:
ISBN-Nummer:

0412040719


This book is the definitive reference on phase-transfer catalysis (PTC), written by the three foremost industrial and academic PTC experts in the world. Phase-Transfer Catalysis, the first practical guide to performing PTC in industry, includes key information and analyses found in no other publication. It will be a valuable resource for synthetic organic chemists, polymer chemists, process chemists, developmental chemists, and chemical engineers in academia and industry. Organic process chemists seeking greater process flexibility, reduced manufacturing costs and pollution, and easier compliance with environmental regulations will find it an indespensable reference. The book provides a thorough introduction to the fundamentals of PTC as a synthetic organic chemistry technique, including reaction mechanisms, selectivity, rates and kinetics. It gives specific guidelines on how to optimize catalyst, solvent, base, hydration, and more, based on reaction characteristics. The section on applications includes nucleophilic displacement reactions, oxidation and reduction reactions, and such special topics as insoluble PTC (triphase catalysis), polymerization, chiral catalysis, applications in environmental and analytical chemistry, and transition metal co-catalyzed PTC. Throughout the book, PTC applications in key industries are discussed--including organic chemicals, polymers, pharmaceuticals, agrichemicals, monomers, petrochemicals, flavors and fragrances, additives, dyes, and specialty chemicals.

Detailangaben zum Buch - Phase-transfer Catalysis by C.m. Starks Hardcover | Indigo Chapters


EAN (ISBN-13): 9780412040719
ISBN (ISBN-10): 0412040719
Gebundene Ausgabe
Taschenbuch
Erscheinungsjahr: 2007
Herausgeber: C.m. Starks
688 Seiten
Gewicht: 1,181 kg
Sprache: eng/Englisch

Buch in der Datenbank seit 2007-06-25T11:48:34+02:00 (Berlin)
Detailseite zuletzt geändert am 2023-02-06T15:16:50+01:00 (Berlin)
ISBN/EAN: 0412040719

ISBN - alternative Schreibweisen:
0-412-04071-9, 978-0-412-04071-9
Alternative Schreibweisen und verwandte Suchbegriffe:
Autor des Buches: halper, starks, mark halpern, lem, liott
Titel des Buches: perspective fundamentals, phase transfer catalysis, industrial catalysis

Daten vom Verlag:

Autor/in: C.M. Starks; M. Halper
Titel: Phase-Transfer Catalysis - Fundamentals, Applications, and Industrial Perspectives
Verlag: Springer; Springer Netherland
668 Seiten
Erscheinungsjahr: 1994-06-30
Dordrecht; NL
Sprache: Englisch
213,99 € (DE)
219,99 € (AT)
236,00 CHF (CH)
Available
XIV, 668 p.

BB; Hardcover, Softcover / Technik/Chemische Technik; Industrielle Chemie und Chemietechnologie; Verstehen; Additiv; Compound; Isomer; Oxidation; Polymer; distribution; liquid; Industrial Chemistry; Characterization and Analytical Technique; Polymers; Chemistry; Werkstoffprüfung; Technische Anwendung von Polymeren und Verbundwerkstoffen; Chemie; BC

1: Basic Concepts in Phase-Transfer Catalysis.- A. Phase-Transfer-Catalyzed Reactions.- B. Basic Steps of Phase-Transfer Catalysis.- C. The PTC Reaction Rate Matrix.- D. Anion Transfer and Anion Activation.- E. Effect of Reaction Variables on Transfer and Intrinsic Rates.- F. Outline of Compounds Used as Phase-Transfer Catalysts.- 2: Phase-Transfer Catalysts: Fundamentals I.- A. Introduction.- B. Structural Factors Affecting the Distribution of Anions Between Aqueous and Organic Phases.- C. Structural Factors Affecting the Distribution of Phase-Transfer Catalyst Cations Between the Aqueous and Organic Phases.- D. Effects of the Organic Phase Polarity on the Distribution of Phase-Transfer Cation-Anion Pairs.- E. Effects of Changes in Organic Phase Polarity During Reaction.- F. Factors Affecting the Distribution of Phase-Transfer Catalyst Cation-Anion Pairs Between an Organic Phase and an Aqueous Phase Containing Hydroxide Ion.- G. Effect of Hydration of the Transferred Anion and the Effect of Inorganic Salt and/or Hydroxide Concentration in the Aqueous Phase.- 3: Phase-Transfer Catalysis: Fundamentals II.- A. Introduction.- B. Liquid-Liquid PTC.- C. Solid-Liquid PTC.- 4: Phase-Transfer Catalysts.- A. Introduction.- B. Use of Quaternary Salts as Phase-Transfer Catalysts.- C. Macrocyclic and Macrobicyclic Ligands.- D. PEGs, Tris (3,6-dioxaheptyl)amine (TDA-1), and Related Ethoxylated Compounds as Phase-Transfer Catalysts.- E. Other Soluble Polymers and Related Multifunctional Compounds as Phase-Transfer Catalysts.- F. Use of Dual PTC Catalysts or Use of Cocatalysts in Phase-Transfer Systems.- G. Catalysts for Transfer of Species Other Than Anions.- H. Separation and Recovery of Phase-Transfer Catalysts.- 5: Insoluble Phase-Transfer Catalysts.- A. Introduction.- B. PTC Catalysts Bound to Insoluble Resins.- C. Phase-Transfer Catalysts Bound to Inorganic Solid Supports.- D. PTC Catalysts Contained in a Separate Liquid Phase (Third-Liquid-Phase Catalyst).- 6: Variables in Reaction Design for Laboratory and Industrial Applications of Phase-Transfer Catalysis.- A. Choice of Catalyst.- B. Choice of Solvent.- C. Presence of Water.- D. Agitation.- E. Choice of Anion, Leaving Group, and Counteranion.- F. Choice of Base.- G. Guidelines for Exploring New PTC Applications.- 7: Phase-Transfer Catalysis Displacement Reactions with Simple Anions.- A. General Considerations.- B. Behavior of Various Anions in PTC Displacement Reactions.- 8: Phase-Transfer Catalysis Reaction with Strong Bases.- A. C-Alkylation.- B. N-Alkylation.- C. O-Alkylation—Etherification.- D. S- Alky lation—Thioetherification.- E. Dehydrohalogenation.- F. Carbene Reactions.- G. Condensation Reactions.- H. Deuterium Exchange, Isomerization, and Oxidation.- 9: Phase-Transfer Catalysis: Polymerization and Polymer Modification.- A. Introduction.- B. Polymer Synthesis.- C. Chemical Modification of Polymers.- 10: Phase-Transfer-Catalyzed Oxidations.- A. Introduction.- B. Permanganate Oxidations.- D. PTC Oxidations with Hydrogen Peroxide.- E. PTC Air or Oxygen Oxidations.- F. Oxidations by Persulfates.- H. PTC Oxidations with Nitric Acid.- I. PTC Carbon Tetrachloride/Sodium Hydroxide Oxidations.- J. PTC Oxidations with Periodate and Related Oxidizing Anions.- K. PTC Oxidations with Perborate.- L. PTC Oxidations with Ferrate and Ferricyanide.- M. PTC Oxidations with Superoxide.- N. PTC Electrochemical Oxidations.- O. PTC Oxidations with Other Oxidants.- 11: Phase-Transfer-Catalyzed Reductions.- A. Sodium Borohydride Reductions.- B. Lithium Aluminum Hydride Reductions.- C. Reductions withSodium Formate.- D. Reductions with Sulfur-Containing Anions.- E. Hydrogenation.- F. Reductions with Formaldehyde.- G. Electrochemical Reduction.- H. Photochemical Reduction.- I. Wolff-Kishner Reduction.- J. Reduction by Dodecarbonyltriiron and Related Species.- 12: Phase-Transfer Catalysis: Chiral Phase-Transfer-Catalyzed Formation of Carbon—Carbon Bonds.- A. Introduction.- B. Alkylation Reactions.- 13: Phase Transfer Catalysis—Transition Metal Cocatalyzed Reactions.- A. Introduction.- B. Carbonylation and Reactions with Carbon Monoxide.- B. PTC Reduction and Hydrogenation with Metal Cocatalysts.- C. Coupling Reactions of Alkenes, Alkynes, and Alkyl Halides.- D. Other Reactions.- 14: Phase-Transfer Catalysis in Analytical Chemistry.- A. The PTC/Analytical Chemistry Match.- B. Esterification, Etherification, and Other Nucleophilic Derivatizations.- C. Non-Nucleophilic PTC Reactions Used in Analytical Chemistry.- 15: Phase-Transfer Catalysis: Industrial Perspectives.- A. Industrial Background.- B. Evaluation of PTC as a Commercial Manufacturing Process Technology.

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