Valeria Arrighi, J.M.G. Cowie:Polymere: Chemie und Physik moderner Materialien: Chemie und Physik von Mo
- Taschenbuch ISBN: 9780849398131
Introduction to Rheology. The book features real world examples, new chapter problems, and a solutions manual. Birth of a Concept. Subtitle Chemistry and Physics of Modern Materials, Thir… Mehr…
Introduction to Rheology. The book features real world examples, new chapter problems, and a solutions manual. Birth of a Concept. Subtitle Chemistry and Physics of Modern Materials, Third Edition. Churchill's Dilemma: The Real Story Behind the Origins of the 1915 Dardanelles Campaign is an entirely original study of the origins of the disastrous Dardanelles Campaign of 1915 and Winston Churchill's role in it. The Nile on eBay FREE SHIPPING UK WIDE Polymers: Chemistry and Physics of Modern Materials by J.M.G. Cowie, Valeria Arrighi Underscoring the multidisciplinary nature of polymer science, this third edition provides a broad-based and comprehensive text at an introductory, reader-friendly level. With nearly 50 percent new or updated material, this edition presents new polymerization methods, characterization techniques, and applications in electronic, biological, and medical settings. new topics include controlled radical polymerization, novel polymer architectures, chain dimension, morphology, determining molecular weights, metallocene catalysts, copolymers, and rheological behavior. The book features real world examples, new chapter problems, and a solutions manual. FORMATPaperback LANGUAGEEnglish CONDITIONBrand New Publisher Description Extensively revised and updated to keep abreast of recent advances, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide a broad-based, high-information text at an introductory, reader-friendly level that illustrates the multidisciplinary nature of polymer science. Adding or amending roughly 50% of the material, this new edition strengthens its aim to contribute a comprehensive treatment by offering a wide and balanced selection of topics across all aspects of the chemistry and physics of polymer science, from synthesis and physical properties to applications. Although the basics of polymer science remain unchanged, significant discoveries in the area of control over molecular weight, macromolecular structure and architecture, and the consequent ability to prepare materials with specific properties receive extensive mention in the third edition. Expanded chapters include controlled radical polymerizations, metallocene chemistry, and the preparation of block and graft copolymers, as well as multiarmed and dendritic structures. Reflecting the growth of polymer applications in industry, the book presents detailed examples to illustrate polymer use in electronic, biological, and medical settings. The authors introduce new understandings of rheological behavior and replace old and outmoded methods of polymer characterization with new and up-to-date techniques. Also new to this edition are a series of problems at the end of each chapter that will test whether the reader has understood the various points and in some cases expand on that knowledge. An accompanying solutions manual is also available for qualifying course adoptions. Offering the highest quality, comprehensive coverage of polymer science in an affordable, accessible format, Polymers: Chemistry and Physics of Modern Materials, Third Edition continues to provide undergraduate and graduate students and professors with the most complete and current coverage of modern polymer science. Table of Contents Introduction Birth of a Concept Some Basic Definitions Synthesis of Polymers NomenclatureAverage Molar Masses and Distributions Size and ShapeConfiguration The Glass Transition Temperature Tg and the Melting Temperature TmElastomers, Fibers, and Plastics Fiber-Forming PolymersPlastics Thermosetting PolymersElastomersStep-Growth PolymerizationGeneral ReactionsReactivity of Functional Groups Carothers Equation Control of the Molar MassStoichiometric Control of MnKinetics Molar Mass Distribution in Linear SystemsAverage Molar Masses Characteristics of Step-Growth PolymerizationTypical Step-Growth ReactionsRing FormationNonlinear Step-Growth ReactionsStatistical DerivationComparison with ExperimentPolyurethanesThermosetting PolymersFree-Radical Addition Polymerization Addition PolymerizationChoice of InitiatorsFree-Radical Polymerization Initiators Chain GrowthTermination Steady-State KineticsHigh-Conversion Bulk PolymerizationsChain Transfer Inhibitors and Retarders Activation Energies and the Effect of TemperatureThermodynamics of Radical PolymerizationHeats of Polymerization Polymerization Processes Features of Free-Radical PolymerizationControlled Radical Polymerization Nitroxide-Mediated Polymerizations Atom Transfer Radical Polymerization (ATRPReverse ATRPDegenerative Chain Transfer Reaction (DT) Reversible Addition Fragmentation Chain Transfer (RAFT) CRP of Vinyl Chloride The Kinetics of CRP Processes Application to Experimental DataIonic Polymerization General CharacteristicsCationic Polymerization Propagation by Cationic Chain Carriers Termination General Kinetic SchemeEnergetics of Cationic PolymerizationTelechelic Polymers via Cationic Polymerization Cationic Ring Opening Polymerization Stable Carbocations Anionic PolymerizationLiving PolymersKinetics and Molar Mass Distribution in Living Anionic Systems Metal Alkyl Initiators Solvent and Gegen Ion EffectsAnionic Ring-opening PolymerizationLinear Copolymers and Other ArchitecturesGeneral CharacteristicsComposition DriftThe Copolymer Equation Monomer Reactivity RatiosReactivity Ratios and Copolymer Structure Monomer Reactivities and Chain Initiation Influence of Structural Effects on Monomer Reactivity Ratios The Q-e Scheme Alternating Copolymers Block Copolymer Synthesis Graft Copolymer Synthesis Statistical and Gradient CopolymersComplex Molecular ArchitecturesDendrimersPolymer Stereochemistry Architecture Orientation Configuration Geometric Isomerism Conformation of Stereoregular Polymers Factors Influencing StereoregulationHomogeneous Stereospecific Cationic PolymerizationsHomogeneous Stereoselective Anionic PolymerizationsHomogeneous Diene PolymerizationSummaryPolymerization Reactions Initiated by Metal Catalysts and Transfer Reactions Polymerization Using Ziegler-Natta CatalystsNature of CatalystNature of Active Centers Bimetallic MechanismMonometallic Mechanism Stereoregulation Ring-Opening Metathesis Polymerization (ROMP) Monocyclic MonomersBicyclo- and Tricyclomonomers Copolyalkenamers Living Systems Group Transfer Polymerization (GTP) Aldol Group Transfer PolymerizationMetallocene CatalystsConcluding Remarks Polymers in SolutionThermodynamics of Polymer SolutionsIdeal Mixtures of Small MoleculesNonideal Solutions Flory-Huggins Theory: Entropy of MixingEnthalpy Change on Mixing Free Energy of Mixing Limitations of the Flory-Huggins Theory Phase EquilibriaFlory-Krigbaum TheoryLocation of the Theta TemperatureLower Critical Solution Temperatures Solubility and the Cohesive Energy Density Polymer-Polymer MixturesKinetics of Phase SeparationPolymer Characterization - Molar Masses IntroductionMolar Masses, Molecular Weights, and SI Units Number-Average Molar Mass MnEnd-Group AssayColligative Properties of Solutions Osmotic Pressure Light Scattering Dynamic Light Scattering ViscosityGel Permeation ChromatographyMaldiPolymer Characterization - Chain Dimensions, Structures, and MorphologyAverage Chain Dimensions Freely Jointed Chain ModelShort-range Effects Chain StiffnessTreatment of Dilute Solution DataNuclear Magnetic Resonance (NMR)Infrared SpectroscopyThermal AnalysisWide-Angle and Small-Angle ScatteringMicroscopy The Crystalline State and Partially Ordered Structures IntroductionMechanism of Crystallization Temperature and Growth Rate MeltingThermodynamic Parameters Crystalline Arrangement of PolymersMorphology and KineticsMorphology Kinetics of CrystallizationBlock Copolymers Historical Development of Polymer Liquid Crystals Liquid Crystalline PhasesIdentification of the MesophasesLyotropic Main-Chain Liquid Crystalline Polymers Thermotropic Main-Chain Liquid Crystal PolymersSide-Chain Liquid Crystalline Polymers Chiral Nematic Liquid Crystal PolymersThe Glassy State and Glass TransitionThe Amorphous State The Glassy StateRelaxation Processes in the Glassy State Glass Transition Region Theoretical Treatments Dependence of Tg on Molar Mass Structural Relaxation and Physical Aging Rheology and Mechanical PropertiesIntroduction to RheologyThe Five Regions of Viscoelastic Behavior The Viscous RegionMechanical Properties Mechanical Models Describing Viscoelasticity Linear Viscoelastic Behavior of Amorphous PolymersDynamic Mechanical and Dielectric Thermal Analysis Time-Temperature Superposition PrincipleDynamic ViscosityA Molecular Theory for ViscoelasticityThe Reptation ModelThe Elastomeric State General IntroductionExperimental VulcanizationProperties of ElastomersThermodynamic Aspects of Rubberlike Elasticity Nonideal ElastomersDistribution Function for Polymer Conformation Statistical ApproachSwelling of Elastomeric NetworksNetwork Defects Resilience of Elastomers Structure-Property Relations General ConsiderationsControl of Tm and TgRelation between Tm andTgRandom Copolymers Dependence of Tm andTg on Copolymer CompositionBlock Copolymers Plasticizers Crystallinity and Mechanical Response Application to Fibers, Elastomers, and PlasticsFibers Aromatic Polyamides PolyethyleneElastomers and Cross-Linked NetworksPlastics High-temperature Speciality Polymers Carbon Fibers Concluding Remarks Polymers for the Electronics IndustryIntroductionPolymer Resists for IC FabricationThe Lithographic ProcessPolymer Resists PhotolithographyElectron Beam Sensitive Resists X-ray and Ion Sensitive Resists Electroactive Polymers Conduction Mechanisms Preparation of Conductive PolymersPolyacetylene Poly(P-phenylene) Polyheterocyclic Systems Polyaniline Poly(Phenylene Sulfide) Poly(1,6-heptadiyne)Applications Photonic ApplicationsLight-Emitting Polymers Nonlinear OpticsLangmuir-Blodgett FilmsOptical Information StorageThermorecording on Liquid Crystalline Polymers Index Long Description Churchill's Dilemma: The Real Story Behind, Taylor & Francis<
