ISBN: 9780470913475

Introduction to Statistical Thermodynamics. 1.2 Macrostates and Microstates. 1.5 The Boltzmann Energy Distribution. The Canonical Partition Function. 2.3 Canonical Partition Function for … Mehr…

Introduction to Statistical Thermodynamics. 1.2 Macrostates and Microstates. 1.5 The Boltzmann Energy Distribution. The Canonical Partition Function. 2.3 Canonical Partition Function for a Molecule with Several Independent Energy Modes. The Nile on eBay   FREE SHIPPING UK WIDE   An Introduction to Applied Statistical Thermodynamics by Stanley I. Sandler * Discusses the analysis of the virial equation of state * Shows how the exact composition dependence of the second virial coefficient derived from statistical thermodynamics has become the basis for mixing rules used with common equations of state. FORMATPaperback LANGUAGEEnglish CONDITIONBrand New Publisher Description With the present emphasis on nano and bio technologies, molecular level descriptions and understandings offered by statistical mechanics are of increasing interest and importance. This text emphasizes how statistical thermodynamics is and can be used by chemical engineers and physical chemists. The text shows readers the path from molecular level approximations to the applied, macroscopic thermodynamic models engineers use, and introduces them to molecular-level computer simulation. Readers of this book will develop an appreciation for the beauty and utility of statistical mechanics. Author Biography STANLEY I. SANDLER is the H. B. du Pont Professor of Chemical Engineering at the University of Delaware as well as professor of chemistry and biochemistry. He is also the founding director of its Center for Molecular and Engineering Thermodynamics. In addition to this book, Sandler is the author of 235 research papers and a monograph, and is the editor of a book on thermodynamic modeling and five conference proceedings. He earned his B.Ch.E. degree in 1962 from the City College of New York, and his Ph.D. in chemical engineering from the University of Minnesota in 1966. Table of Contents 1. Introduction to Statistical Thermodynamics. 1.1 Probabistic Description. 1.2 Macrostates and Microstates. 1.3 Quantum Mechanics Description of Microstates. 1.4 The Postulates of Statistical Mechanics. 1.5 The Boltzmann Energy Distribution. 2. The Canonical Partition Function. 2.1 Some Properties of the Canonical Partition Function. 2.2 Relationship of the Canonical Partition Function to Thermodynamic Properties. 2.3 Canonical Partition Function for a Molecule with Several Independent Energy Modes. 2.4 Canonical Partition Function for a Collection of Noninteracting Identical Atoms. Problems. 3. The Ideal Monatomic Gas. 3.1 Canonical Partition Function for the Ideal Monatomic Gas. 3.2 Identification of b as 1/kT. 3.3 General Relationships of the Canonical Partition Function to Other Thermodynamic Quantities. 3.4 The Thermodynamic Properties of the Ideal Monatomic Gas. 3.5 Energy Fluctuations in the Canonical Ensemble. 3.6 The Gibbs Entropy Equation. 3.7 Translational State Degeneracy. 3.8 Distinguishability, Indistinguishability and the Gibbs' Paradox. 3.9 A Classical Mechanics – Quantum Mechanics Comparison: The Maxwell-Boltzmann Distribution of Velocities. Problems. 4. Ideal Polyatomic Gas. 4.1 The Partition Function for an Ideal Diatomic Gas. 4.2 The Thermodynamic Properties of the Ideal Diatomic Gas. 4.3 The Partition Function for an Ideal Polyatomic Gas. 4.4 The Thermodynamic Properties of an Ideal Polyatomic Gas. 4.5 The Heat Capacities of Ideal Gases. 4.6 Normal Mode Analysis: the Vibrations of a Linear Triatomic Molecule. Problems. 5. Chemical Reactions in Ideal Gases. 5.1 The Non-Reacting Ideal Gas Mixture. 5.2 Partition Function of a Reacting Ideal Chemical Mixture. 5.3 Three Different Derivations of the Chemical Equilibrium Constant in an Ideal Gas Mixture. 5.4 Fluctuations in a Chemically Reacting System. 5.5 The Chemically Reacting Gas Mixture. The General Case. 5.6 An Example. The Ionization of Argon. Problems. 6. Other Partition Functions. 6.1 The Microcanonical Ensemble. 6.2 The Grand Canonical Ensemble. 6.3 The Isobaric-Isothermal Ensemble. 6.4 The Restricted Grand or Semi Grand Canonical Ensemble. 6.5 Comments on the Use of Different Ensembles. Problems. 7. Interacting Molecules in a Gas. 7.1 The Configuration Integral. 7.2 Thermodynamic Properties from the Configuration Integral. 7.3 The Pairwise Additivity Assumption. 7.4 Mayer Cluster Function and Irreducible Integrals. 7.5 The Virial Equation of State. 7.6 The Virial Equation of State for Polyatomic Molecules. 7.7 Thermodynamic Properties from the Virial Equation of State. 7.8 Derivation of Virial Coefficient Formulae from the Grand Canonical Ensemble. 7.9 Range of Applicability of the Virial Equation. Problems. 8. Intermolecular Potentials and the Evaluation of the Second Virial Coefficient. 8.1 Interaction Potentials for Spherical Molecules. 8.2 Interaction Potentials Between Unlike Atoms. 8.3 Interaction Potentials for Nonspherical Molecules. 8.4 Engineering Applications/Implications of the Virial Equation of State. Problems. 9. Monatomic Crystals. 9.1 The Einstein Model of a Crystal. 9.2 The Debye Model of a Crystal. 9.3 Test of the Einstein and Debye Models for a Crystal. 9.4 Sublimation Pressures of Crystals. 9.5 A Comment of the Third Law of Thermodynamics. Problems. 10. Simple Lattice Models of Fluids. 10.1 Introduction. 10.2 Development of Equations of State from Lattice Theory. 10.3 Activity Coefficient Models for Similar Size Molecules from Lattice Theory. 10.4 Flory-Huggins and Other Models for Polymer Systems. 10.5 The Ising Model. Problems. 11. Interacting Molecules in a Dense Fluid. Configurational Distribution Functions. 11.1 Reduced Spatial Probability Density Functions. 11.2 Thermodynamic Properties from the Pair Correlation Function. 11.3 The Pair Correlation Function (Radial Distribution Function) at Low Density. 11.4 Methods of Determination of the Pair Correlation Function at High Density 11.5 Fluctuations in the Number of Particles and the Compressibility Equation 11.6 Determination of the Radial Distribution Function of Fluids using Coherent X-ray or Neutron Scattering. 11.7 Determination of the Radial Distribution Functions of Molecular Liquids. 11.8 Determination of the Coordination Number from the Radial Distribution Function. 11.9 Determination of the Radial Distribution Function of Colloids and Proteins. Problems. 12. Integral Equation Theories for the Radial Distribution Function. 12.1 The Potential of Mean Force. 12.2 The Kirkwood Superposition Approximation. 12.3 The Ornstein-Zernike Equation. 12.4 Closures for the Ornstein-Zernike Equation. 12.5 The Percus-Yevick Equation of State. 12.6 The Radial Distribution Function and Thermodynamic Properties of Mixtures. 12.7 The Potential of Mean Force. 12.8 Osmotic Pressure and the Potential of Mean Force for Protein and Colloidal Solutions. Problems. 13. Computer Simulation. 13.1 Introduction to Molecular Level Simulation. 13.2 Thermodynamic Properties from Molecular Simulation. 13.3 Monte Carlo Simulation. 13.4 Molecular Dynamics Simulation. Problems. 14. Perturbation Theory. 14.1 Perturbation Theory for the Square-Well Potential. 14.2 First Order Barker-Henderson Perturbation Theory. 14.3 Second Order Perturbation Theory. 14.4 Perturbation Theory Using Other Potentials. 14.5 Engineering Applications of Perturbation Theory. Problems. 15. Debye-Hückel Theory of Electrolyte Solutions. 15.1 Solutions Containing Ions (and electrons). 15.2 Debye-Hückel Theory. 15.3 The Mean Ionic Activity Coefficient. Problems. 16. The Derivation of Thermodynamic Models from the Generalized van der Waals Partition Function. 16.1 The Statistical Mechanical Background. 16.2 Application of the Generalized van der Waals Partition Function to Pure Fluids. 16.3 Equation of State for Mixtures from the Generalized van der Waals Partition Function. 16.4 Activity Coefficient Models from the Generalized van der Waals Partition Function. 16.5 Chain Molecules and Polymers. 16.6 Hydrogen-bonding and Associating Fluids. Problems. Feature 1. Introduction to Statistical Thermodynamics 2. The Canonical Partition Function 3. The Ideal Monatomic Gas 4. Ideal Polyatomic Gas 5. Chemical Reactions in Ideal Gases 6. Other Partition Functions 7. Interacting Molecules in a Gas 8. Intermolecular Potentials and the Evaluation of the SecondVirial Coefficient 9. Monatomic Crystals 10. Simple Lattice Models of Fluids 11. Interacting Molecules in a Dense Fluid. ConfigurationalDistribution Functions 12. Integral Equation Theories for the Radial DistributionFunction 13. Computer Simulation 14. Perturbation Theory 15. Debye-H Details ISBN0470913479 Author Stanley I. Sandler Short Title INTRO TO APPLIED STATISTICAL T Language English ISBN-10 0470913479 ISBN-13 9780470913475 Media Book Format Paperback Illustrations Yes Year 2010 Birth 1940 Edition 1st Imprint John Wiley & Sons Inc Place of Publication New York Country of Publication United States NZ Release Date 2010-11-16 UK Release Date 2010-11-16 Pages 368 Publisher John Wiley & Sons Inc Publication Date 2010-12-10 DEWEY 541.369 Audience Undergraduate US Release Date 2010-12-10 AU Release Date 2010-10-26 We've got thisAt The Nile, if you're looking for it, we've got it.With fast shipping, low prices, friendly service and well over a million items - you're bound to find what you want, at a price you'll love! 30 DAY RETURN POLICYNo questions asked, 30 day returns! FREE DELIVERYNo matter where you are in the UK, delivery is free. SECURE PAYMENTPeace of mind by paying through PayPal and eBay Buyer Protection TheNile_Item_ID:137293770; , Festpreisangebot, [LT: FixedPrice], ISBN-13: 9780470913475, Book Title: An Introduction to Applied Statistical Thermodynamics, Publication Year: 2010, Type: Textbook, Format: Paperback, Language: English, Publication Name: An Introduction to Applied Statistical Thermodynamics, Item Height: 251mm, Item Width: 204mm, Subject: Chemistry, Item Weight: 668g, Number of Pages: 368 Pages, John Wiley & Sons INC International Concepts<

2010, ISBN: 0470913479

Taschenbuch

[EAN: 9780470913475], Neubuch, [PU: John Wiley & Sons, New York], Paperback. One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the funda… Mehr…

[EAN: 9780470913475], Neubuch, [PU: John Wiley & Sons, New York], Paperback. One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the fundamental ideas and engineering uses of statistical thermodynamics, and the equilibrium part of the statistical mechanics. This text emphasises on nano and bio technologies, molecular level descriptions and understandings offered by statistical mechanics. It provides an introduction to the simplest forms of Monte Carlo and molecular dynamics simulation (albeit only for simple spherical molecules) and user-friendly MATLAB programs for doing such simulations, and also some other calculations. The purpose of this text is to provide a readable introduction to statistical thermodynamics, show its utility and the way the results obtained lead to useful generalisations for practical application. The text also illustrates the difficulties that arise in the statistical thermodynamics of dense fluids as seen in the discussion of liquids. * Discusses the analysis of the virial equation of state * Shows how the exact composition dependence of the second virial coefficient derived from statistical thermodynamics has become the basis for mixing rules used with common equations of state. Shipping may be from our UK warehouse or from our Australian or US warehouses, depending on stock availability., Books<

2010, ISBN: 0470913479

Taschenbuch

[EAN: 9780470913475], Neubuch, [PU: John Wiley & Sons, New York], Paperback. One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the funda… Mehr…

[EAN: 9780470913475], Neubuch, [PU: John Wiley & Sons, New York], Paperback. One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the fundamental ideas and engineering uses of statistical thermodynamics, and the equilibrium part of the statistical mechanics. This text emphasises on nano and bio technologies, molecular level descriptions and understandings offered by statistical mechanics. It provides an introduction to the simplest forms of Monte Carlo and molecular dynamics simulation (albeit only for simple spherical molecules) and user-friendly MATLAB programs for doing such simulations, and also some other calculations. The purpose of this text is to provide a readable introduction to statistical thermodynamics, show its utility and the way the results obtained lead to useful generalisations for practical application. The text also illustrates the difficulties that arise in the statistical thermodynamics of dense fluids as seen in the discussion of liquids. * Discusses the analysis of the virial equation of state * Shows how the exact composition dependence of the second virial coefficient derived from statistical thermodynamics has become the basis for mixing rules used with common equations of state. Shipping may be from multiple locations in the US or from the UK, depending on stock availability., Books<

ISBN: 9780470913475

One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the fundamental ideas and engineering uses of statistical thermodynamics, and the equi… Mehr…

One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the fundamental ideas and engineering uses of statistical thermodynamics, and the equilibrium part of the statistical mechanics. This text emphasises on nano and bio technologies, molecular level descriptions and understandings offered by statistical mechanics. It provides an introduction to the simplest forms of Monte Carlo and molecular dynamics simulation (albeit only for simple spherical molecules) and user-friendly MATLAB programs for doing such simulations, and also some other calculations. The purpose of this text is to provide a readable introduction to statistical thermodynamics, show its utility and the way the results obtained lead to useful generalisations for practical application. The text also illustrates the difficulties that arise in the statistical thermodynamics of dense fluids as seen in the discussion of liquids. | An Introduction to Applied Statistical Thermodynamics by Stanley I. Sandler Paperback | Indigo Chapters Books > Science & Nature > Science > Chemistry P10117, Stanley I. Sandler<

2010, ISBN: 9780470913475

Buch, Softcover, [PU: John Wiley & Sons Inc], John Wiley & Sons Inc, 2010