Combustion Chemistry - gebunden oder broschiert

EAN (ISBN-13): 9780387909639
ISBN (ISBN-10): 038790963X
Gebundene Ausgabe
Erscheinungsjahr: 1984
Herausgeber: Springer

Buch in der Datenbank seit 2010-07-21T12:04:01+02:00 (Berlin)
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ISBN/EAN: 038790963X

ISBN - alternative Schreibweisen:
0-387-90963-X, 978-0-387-90963-9
Alternative Schreibweisen und verwandte Suchbegriffe:
Autor des Buches: gardiner, troe, warnatz, dixon
Titel des Buches: combustion chemistry

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Daten vom Verlag:

Autor/in: W. C. Jr. Gardiner
Titel: Combustion Chemistry
Verlag: Springer; Springer US
509 Seiten
Erscheinungsjahr: 1984-11-07
New York; NY; US
Gewicht: 0,900 kg
Sprache: Englisch
85,55 € (DE)
87,95 € (AT)
106,60 CHF (CH)
Not available, publisher indicates OP

BB; Book; Hardcover, Softcover / Technik/Chemische Technik; Industrielle Chemie und Chemietechnologie; Verstehen; modeling; chemistry; combustion; model; computer; C; Industrial Chemistry/Chemical Engineering; Chemistry and Materials Science; Physical Chemistry; Power Electronics, Electrical Machines and Networks; Physikalische Chemie; Elektrotechnik; BB; BC; EA

1. Introduction to Combustion Modeling.- 1. Terminology of reaction kinetics.- 2. Rate laws and reaction mechanisms.- 3. Physical constraints on gas-phase combustion reactions.- 4. Differential equations of homogeneous reaction without transport.- 4.1. Constant-density isothermal reaction.- 4.2. Constant-density adiabatic reaction.- 4.3. Constant-pressure adiabatic reaction.- 4.4. Reactive steady flow.- 5. Methods of numerical integration.- 6. Interpretation of combustion modeling profiles.- 7. References.- 2. Computer Modeling of Combustion Reactions in Flowing Systems with Transport.- 1. Introduction.- 2. Conservation or continuity equations, and other useful relations.- 2.1. Conservation of total mass.- 2.2. Conservation of y-direction momentum.- 2.3. Species equations. Conservation of atoms.- 2.4. Conservation of energy.- 2.5. Auxiliary equations.- 2.6. Eulerian and Langrangian coordinate reference frames.- 2.7. Space integral rate.- 3. Formulation of transport fluxes.- 3.1. Transport processes in mixtures of nonpolar gases.- 3.2. Mixtures containing one polar component.- 3.3. Application of the extended Chapman-Enskog procedure to reactive flow systems.- 3.4. Approximate equations for transport fluxes in multicomponent mixtures.- 4. One-dimensional premixed laminar flame properties by solution of the time-dependent equations.- 4.1. Preliminary transformations.- 4.2. Finite-difference formulation.- 4.3. Solution of equations.- 4.4. The convection term. Lagrangian and Eulerian calculations.- 4.5. Gasdynamic effects.- 5. Premixed laminar flames and kinetic studies.- 6. Two further solution techniques.- 6.1. Newton-type iteration around stationary flame equations.- 6.2. Finite-element collocation method.- 7. Implicit methods and general reactive flow problems.- 7.1. Boundary layer flows.- 7.2. Counterflow flame geometries. Stretched one-dimensional flames.- 7.3. Multidimensional flows.- 8. Operator splitting techniques in multidimensional systems.- 9. Chemical quasi-steady-state and partial equilibrium assumptions in reactive flow modeling.- 10. Concluding remarks.- 11. Nomenclature.- 12. References.- 3. Bimolecular Reaction Rate Coefficients.- 1. Introduction.- 2. Fundamental concepts.- 2.1. The rate coefficient and the Arrhenius equation.- 2.2. Thermodynamic predictions.- 2.3. Macroscopic and microscopic kinetics.- 3. Theoretical predictions of bimolecular reaction rate coefficients.- 3.1. Collision theory.- 3.2. Transition-state theory.- 4. Comparison between experiment and theory for rate coefficients of selected bimolecular gas reactions.- 4.1. O + H2 ? OH + H.- 4.2. OH + H2 ? H2O + H.- 4.3. O + CH4 ? OH + CH3.- 4.4. OH + CO ? CO2 + H.- 5. Summary and conclusions.- 6. Acknowledgments.- 7. References.- 4. Rate Coefficients of Thermal Dissociation, Isomerization, and Recombination Reactions.- 1. Introduction.- 2. General mechanism of thermal dissociation and recombination reactions.- 3. Low-pressure rate coefficients.- 4. High-pressure rate coefficients.- 5. Rate coefficients in the intermediate fall-off range.- 6. Conclusions.- 7. References.- 5. Rate Coefficients in the C/H/O/System.- 1. Introduction.- 1.1. Principles.- 1.2. Organization.- 1.3. Earlier reviews of rate data on hydrocarbon combustion.- 2. General features of high-temperature hydrocarbon combustion.- 2.1. Radical-poor situation: ignition and induction periods.- 2.2. Radical-rich situation: flame propagation.- 3. Reactions in the H2/O2 system.- 3.1 Reactions in the H2/O2 system not involving HO2 or H2O2.- 3.2. Formation and consumption of HO2.- 3.3. Formation and consumption of H2O2.- 4. Reactions of CO and CO2.- 5. Reactions of C1-hydrocarbons.- 5.1. Reactions of CH4.- 5.2. Reactions of CH3.- 5.3. Reactions of CH2O.- 5.4. Reactions of CHO.- 5.5. Reactions of CH2.- 5.6. Reactions of CH.- 5.7. Reactions of CH3OH and CH3O/CH2OH.- 6. Reactions of C2-hydrocarbons.- 6.1. Reactions of C2H6.- 6.2. Reactions of C2H5.- 6.3. Reactions of C2H4.- 6.4. Reactions of C2H3.- 6.5. Reactions of C2H2.- 6.6. Reactions of C2H.- 6.7. Reactions of CH3CHO and CH3CO.- 6.8. Reactions of CH2CO and CHCO.- 7. Reactions of C3- and C4-hydrocarbons.- 7.1. Thermal decomposition and attack of H, O, OH, and HO2 on propane and butane.- 7.2. Thermal decomposition of C3H7 and C4H9.- 7.3. Reactions of propene and butene.- 7.4. Reactions of C3H4 and C4H2.- 8. Mechanism of small hydrocarbon combustion.- 9. Acknowledgments.- 10. References.- 6. Survey of Rate Constants in the N/H/O System.- 1. Introduction.- 2. Organization.- 3. N/O reaction survey.- 3.1. O + N2?N + NO.- 3.2. O + NO ? N + O2.- 3.3. NO + M ? N + O + M.- 3.4. N2O + M ?N2 + O + M.- 3.5. O + N2O ? NO + NO.- 3.6. O + N2O?N2 + O2.- 4. N/H reaction survey.- 4.1. NH3 + M ? NH2 + H + M.- 4.2. NH3 + M ? NH + H2 + M.- 4.3. H + NH3 ? NH2 + H2.- 4.4. H + NH2 ? NH + H2.- 5. N/H/O reaction survey.- 5.1. NH3 + OH ? NH2 + H2O.- 5.2 NH3 + O ? NH2 + OH.- 5.3. HO2 + NO ? NO2 + OH.- 5.4. H + NO ? N + OH.- 5.5. NH + NO ? N2O + H.- 5.6. H + N2O ? N2 + OH.- 5.7. NH2 + O2 ? products.- 5.8. NH2 + NO ? products.- 6. N/H/O rate constant compilation.- 7. References.- 7. Modeling.- 1. Introduction.- 2. Basic concepts and definitions.- 3. Construction of models.- 3.1. The nature of a model.- 3.2. Empirical models.- 3.3. Physical models.- 4. Parameter estimation.- 4.1. Preliminary remarks.- 4.2. Linear models.- 4.3. Nonlinear models.- 5. Adequacy of fit.- 6. Design of experiments.- 7. Dynamic models in chemical kinetics.- 7.1. Preliminary remarks.- 7.2. Trial models.- 7.3. Sensitivity analysis.- 7.4. Optimization and interpretation of results.- 7.5. Further look at sensitivities.- 8. Closing remark.- 9. Acknowledgments.- 10. References.- 8. Thermochemical Data for Combustion Calculations.- 1. Introduction.- 2. The polynomial representation.- 3. Extrapolation.- 4. Thermochemical data sources.- 5. Approximation methods.- 6. Thermochemical polynomials in combustion chemistry.- 7. Required accuracy of thermochemical information.- 8. Acknowledgment.- 9. References.- Appendix A Program for finding coefficients of NASA Polynomials.- Appendix B Program Written by A. Lifshitz and A. Burcat for Evaluating the Coefficients of the Wilhoit Polynomials.- Appendix C Table of Coefficient Sets for NASA Polynomials.